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lx%,FVAL <br /> metal and liberate hydrogen and/or toxic gases. Can initiate polymerization in certain alkenes. Reacts with <br /> cyanide salts and compounds to release gaseous hydrogen cyanide.Flammable and/or toxic gases are also often <br /> generated by reactions with dithiocarbamates, isocyanates;mercaptans,nitrides,nitriles, sulfides, and weak or <br /> strong reducing agents.Additional gas-generating reactions may occur with sulfites,nitrites, thiosulfates(to <br /> give H2S and S03), dithionites(SO2),and carbonates. Can catalyze(increase the rate of)chemical reactions. <br /> Decomposes when heated to the boiling point to produce very toxic and corrosive hydrogen fluoride gas, <br /> Belongs to the Following Reactive Group(s) <br /> ® Acids,Strong Non-oxidizing <br /> a Halogenating Agents <br /> Potentially Incompatible absorbents <br /> Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed <br /> below. <br /> • Cellulose-Based Absorbents <br /> • Mineral-Based&Clay-Based Absorbents <br /> • Sand <br /> • Dirt/Earth <br /> Response Recommendations <br /> Isolation and Evacuation <br /> Excerpt from GUIDE 154 [Substances.-Toxic and/or Corrosive(Non-Combustible)]: <br /> As an immediate precautionary measure;isolate spill or leak area in all direction_ s for at least 50 meters(150 <br /> feet)for liquids and at least 25 meters(75 feet)for solids. <br /> SPILL:Increase,in the downwind direction, as necessary,the isolation distance shown above. <br /> FIRE: If tank,rail car or tank truck is involved in a fire,ISOLATE for 800 meters (1/2 mile)in all directions; <br /> also,consider initial evacuation for 800 meters(1/2 mile)in all directions. (ERG,2012) <br /> Firefighting <br /> Excerpt from GUIDE 154 [Substances-Toxic and/or Corrosive(Non-Combustible)]: <br /> SMALL FIRE: Dry chemical,CO2 or water spray. <br /> LARGE FIRE: Dry chemical,CO2, alcohol-resistant foam or water spray.Move containers from fire area if <br /> you can do it without risk.Dike fire-control water for later disposal;do not scatter the material. <br /> FIRE INVOLVING TANKS OR CAR/TRAILER LOADS Fight fire from maximum distance or use <br /> unmanned hose holders or monitor nozzles.Do not get water inside containers.Cool containers with flooding <br /> quantities of water until well after fire is out.Withdraw immediately in case of rising sound from venting safety <br /> devices or discoloration of tank.ALWAYS stay away from tanks engulfed in fire. (ERG,2012) <br /> Non-Fire Response <br /> Excerpt from GUIDE 154[Substances-Toxic and/or Corrosive(Non-Combustible)]: <br /> http://l27.0.0.1:54673/report?key=CH9379 4/15/2015 <br />