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ODOR CONTROL STUDY <br /> Representative samples were taken from point and area sources . Laboratory and field <br /> analyses of the samples were performed to identify the odorous compounds found in <br /> the emissions . Mass odor emission rates were then calculated for each treatment <br /> process . <br /> An USEPA validated flux-chamber was used to collect samples from the following area <br /> sources : <br /> • Anoxic Tank <br /> Pre-Oxygen Zone in Oxidation Ditch ( prior to aerators ) <br /> Mixed -Aerated Zone in Oxidation Ditch (after aerators ) <br /> Sludge Storage Basins <br /> • Septage Storage Tanks <br /> • Filtrate Sump <br /> Samples were also taken and analyzed for several point sources , including : <br /> • Headworks Scrubber ( inlet and outlet) <br /> • Combined Sludge Storage Duct (duct from Sludge and Septage Storage Tanks <br /> to the RSF -Scrubber) <br /> • RSF Scrubber -( inlet and outlet) <br /> Figure 1 provides an overview of the facilities that were included in the mass odor <br /> emissions inventory for the Central WWTF. <br /> 2 . 1 Air Emission Testing Methodologies <br /> Emissions from Wastewater Treatment Facilities and sludge processing facilities <br /> typically contain high amounts of H2S and organic sulfur compounds . These compounds <br /> are known to be highly odorous at low concentrations . Table 1 shows that these <br /> compounds can be detected by the human olfactory system at less than part per billion <br /> by volume ( ppbv) concentrations . Thus , H2S and organic sulfur compounds were the <br /> primary odorous compounds measured during the sampling program . <br /> H2S concentrations were measured at the plant using a Jerome 631X H2S detector and <br /> colorimetric sorption tubes . In addition , samples from all of the area and point sources <br /> were analyzed on -site for organic sulfur compounds using a field portable gas <br /> chromatography/mass spectrometry (GC/MS ) unit. Samples were also collected in <br /> preconditioned Tedlar gas sampling bags and sent to a laboratory for olfactory analysis . <br /> Additional information on the testing methodologies used to measure odor emissions <br /> from the Central WWTF is provided below: <br /> • A Jerome Model 631X total sulfide analyzer was used for real-time measurement <br /> of all sulfur compounds , in terms of H2S concentrations . The meter is <br /> quantitatively calibrated for H2S . However, organic sulfur compounds are also <br /> measured by the analyzer, but at fractional proportions . <br /> .� 3 Indian River County, Central Wastewater Treatment Facility <br /> J PBSU #071230, February 2003 <br />