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ODOR CONTROL STUDY <br /> the scrubbers . By contrast , the Headworks scrubber appears to be removing 95 % of <br /> H2S that enters the scrubber. The low sulfur removal rate for the RSF scrubber is not <br /> surprising because the scrubber lacks controls for the dynamic sulfur loads that are <br /> delivered to the scrubber. Blowdown rates are also uncontrolled . In addition , the <br /> scrubber uses caustic soda (sodium hydroxide ) for H2S removal . Caustic soda is not <br /> effective at removing organic sulfur compounds . Organic sulfur compounds must be <br /> oxidized by chlorine . Therefore , the chemistry in the scrubber and the controls will have <br /> to be changed in order to improve the effectiveness of the RSF scrubber. <br /> 2 . 3 . 3 Regional Sludge Facility Sulfur Mass Balance <br /> A sulfur mass balance was performed for the RSF in order to assess the effectiveness <br /> of existing odor control systems to capture and treat sulfur emissions . Figure 8 shows a <br /> sulfur mass balance using Jerome measurements . All concentrations and flow rates <br /> represent actual field measurements , except the concentration and flow rate for the <br /> Dewatering Building . A proper sampling point could not be located for this point <br /> because the new hoods and covers for belt filter presses were not connected at the time <br /> of sampling . Therefore , the Dewatering Building concentration and airflow rate were <br /> calculated by assuming a closed mass balance . <br /> As can be seen in Table 5 , the calculated concentration for the Dewatering Building is <br /> nearly equivalent to the measured H2S concentrations in the ambient air within the <br /> Dewatering Building . This provides a high degree of confidence in the field <br /> measurements and the accuracy of the mass odor emissions inventory. Using this mass <br /> balance , fugitive emission rates were computed for the Sludge and Septage Storage <br /> Tanks and the overall RSF . A comparison of colorimetric sulfur emissions from the <br /> surface of the Sludge and Septage Storage Tanks to the Jerome sulfur flow rate in the <br /> combined sludge storage duct shows that approximately 75 % of the emissions from the <br /> Sludge and Septage Storage Tanks were captured and delivered to the existing <br /> scrubber. This means that 25 % of the sulfur emissions were being emitted into the <br /> atmosphere as fugitive emissions . These emissions are escaping the collection system <br /> through openings in the top of the tank. Many dampers in the odor collection system <br /> were closed during the sampling program . Thus , fugitive emissions could be reduced if <br /> the dampers were opened and openings in the tanks were closed . This estimate of <br /> fugitive emissions must be considered somewhat soft (could be significantly higher or <br /> lower) because of the dynamic nature of the facility and the difficulty in measuring <br /> fugitive air emissions . <br /> 2 . 3 . 4 Impact of . Dewatering Operations on Emissions <br /> Operators at the Central WWTF indicated that odor emissions from the plant appeared <br /> to increase when the belt filter presses were dewatering sludge . Specifically, the <br /> operators could detect higher odors at the Filtrate Equalization Basin and the liquid <br /> treatment processes . Filtrate from the belt filter presses flowed to the Filtrate <br /> Equalization Basin , where it is stored and then pumped to the liquid treatment <br /> 10 Indian River County, Central Wastewater Treatment Facility <br /> PBSW #071230, February 2003 <br />