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ORDINANCE NO. 2007-013 an accidental discharge or accidental spill into the POTW of such newly identified hazardous waste. (F) In the case of any notification made under section 201.78, the user shall certify that it has or will have a program, approved by the County Administrator, in place within 30 days of the time of notification to prevent or minimize the chances of additional accidental discharges of hazardous waste into the POTW. t (G) This provision does not create a right to discharge any substance not otherwise permitted to be discharged by this Ordinance, a permit issued hereunder, or any applicable Federal or State law. (H) The County Administrator, under this Part, may hold the user responsible for all costs incurred by the County due to repairs resulting from discharge to the POTW, cleanup, and any necessary steps taken to protect the operations of the POTW as a result of the discharge of hazardous waste into the system. SECTION 21. CREATION OF NEW SECTION 201.79 OF THE CODE Commencing on the Effective Date of this Ordinance, the following section is created to read as follows: Section 201.79. Additional Requirements Applicable to Reports Provided Pursuant to Sections 201.76. 201.77: and 201.78 of this Part. (A) Analytical Requirements. All pollutant analyses, including sampling techniques, to be submitted as part of a wastewater discharge permit application or report shall be performed in accordance with the techniques prescribed in 40 CFR Part 136, unless otherwise specified in an applicable categorical pretreatment standard. If 40 CFR Part 136 does not contain sampling or analytical techniques for the pollutant in question, sampling and analyses must be performed in accordance with procedures approved by EPA and/or FDEP. (B) Sample Collection (1) Except as set forth in section 201.79(B)(2) of this Part, the User must collect wastewater samples using flow proportional composite collection techniques. In the event flow proportional sampling is infeasible, the County Administrator may authorize the use of time proportional sampling or a minimum of four (4) grab samples where the user demonstrates that this will provide a representative sample of the effluent being discharged. In addition, grab samples may be required to show compliance with instantaneous discharge limits. (2) Samples for oil and grease, temperature, pH, cyanide, phenols, sulfides, and volatile organic compounds must be obtained using grab collection techniques.